Explain the following reactions with suitable example : (i) (ii) Swarts reaction... (iv) Wurtz-Fitting reaction (v) Friedel-Craft’s alkylation reaction... Finkelstein reaction... Write the major products and name the rule responsible for the formation of the product... Write the difference between (i) (ii) retention and inversion of ...
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57) Provide the structure of the major organic product in the following reaction sequence. 58) Provide the structure of the major organic product(s) in the following reaction. 59) Provide the structure of the major organic product(s) in the following reaction.

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  • In the following reaction, o-toluidine is the direct-substitution product; m-toluidine is the cine-substitution product. Benzyne is an extremely reactive species. In Section 6.3, we saw that in a molecule with a triple bond, the two sp hybridized carbons and the atoms attached to these car- bons are linear because the bond angles are 180°.
  • (a) OCH3 (b) NH2 (c) NO2 Br Cl Br Solution: The substitutions will occur at the positions marked by asterisk (a) OCH3 (b) NH2 (c) NO2 Cl Br * * * * Br * * 16.16 Show the major products from reaction of following substances with (i) CH3CH2Cl, AlCl3 and (ii) HNO3,H2SO4 Cl (a) (b) O Solution: (a) Cl 1 CH3CH2Cl,AlCl3 Cl Cl Cl Cl HNO 3 ...

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Reaction kinetics: CH3 CH3 rate = k [RX]. i. The carbonyl carbon has a sizable partial positive charge. ii. In an SN1 reaction a s bond must break in the rate-determining step, which requires more energy than the shift of a pair of p electrons, which is what happens in a tetrahedral mechanism. iii.

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Brown 5e ISV SM 9 1 Chapter 9 Benzene and Its Derivatives Problems 9 1 Which of the following compounds are aromatic Compound b is not aromatic because even

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• CH3. H-O2HO2 H BH3. 4. Show an arrow mechanism for the following transformation.

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Predict the reaction of ozone O3 in (CH3)2S ozonolysis. Ozonolysis of Alkenes: Ozonolysis involves the oxidative cleavage of alkenes and alkynes to give carbonyl compounds like aldehydes, ketones ...

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The reaction of an alkyl halide with aqueous KOH - Alkyl halide when treated with Aqueous KOH, Alcohol is obtained.-as we know that: fig. ortho directing will come because at pera steric stress will come and para of Br wll be at less -I effrct so majority will come there OH group for H + Option 1) Option 2) Option 3) Option 4)

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72) Provide the major organic product of the reaction shown below. Answer: Diff: 2. Section: 14.8 . 73) Provide the major organic product of the reaction shown below. Answer: Br(CH2)6Br. Diff: 2. Section: 14.8. 74) Predict the products of the following reaction and give a reasonable mechanism for their formation. Answer: Diff: 2. Section: 14.8

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AlCl3 CH3 CH3 OCH3 2 (c) (d) 1 CH3 3 2 CH3 2 2 OCH3 1.15 All of the following species are isoelectronic, that is, they have the same number of electrons bonding the same number of atoms. Determine which atoms have a formal charge. Calculate the net charge for each species. (a) 1.16 C (b) O N (b) O N (b) S (c) N (d) O N C O (e) S O (b) Br (c) (d ...

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Nov 21, 2012 · Given what we know about SN1, SN2, E1, and E2 reactions, we can say the following: The “big barrier” to the SN2 reaction is steric hindrance. The rate of SN2 reactions goes primary > secondary > tertiary; The “big barrier” to the SN1 and E1 reactions is carbocation stability.

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